·Marin-Luna, M.; Vidal, A.; Bautista, D.; Orenes, R.-A.; Alajarin, M. Acid-promoted cycloisomerization of phenylallenes bearing acetalic functions at the ortho position: a stereocontrolled entry to indeno-fused dioxepanes, dioxocanes and thio-analogs. Organic & Biomolecular Chemistry, 2015, 13, 8420–8424. http://doi.org/10.1039/C5OB00897B
·Martinez-Cuezva, A.; Valero-Moya, S.; Alajarin, M.; Berna, J. Light-responsive peptide [2]rotaxanes as gatekeepers of mechanised nanocontainers. Chemical Communications, 2015, 51, 14501–14504. http://doi.org/10.1039/C5CC04356D
·Martinez-Cuezva, A.; Rodrigues, L. V.; Navarro, C.; Carro-Guillen, F.; Buriol, L.; Frizzo, C. P.; … Berna, J. Dethreading of Tetraalkylsuccinamide-Based [2]Rotaxanes for Preparing Benzylic Amide Macrocycles. Journal of Organic Chemistry, 2015, 80, 10049–10059. http://doi.org/10.1021/acs.joc.5b01651
·Martinez-Cuezva, A.; Pastor, A.; Cioncoloni, G.; Orenes, R.-A.; Alajarin, M.; Symes, M. D.; Berna, J. Versatile control of the submolecular motion of di(acylamino)pyridine-based [2]rotaxanes. Chemical Science, 2015, 6, 3087–3094. http://doi.org/10.1039/C5SC00790A
·Caravaca, M.; Sanchez-Andrada, P.; Soto, A.; Alajarin, M. The network simulation method: a useful tool for locating the kinetic-thermodynamic switching point in complex kinetic schemes. Physical Chemistry Chemical Physics, 2014, 16, 25409–25420. http://doi.org/10.1039/C4CP02079K
·Lopez-Leonardo, C.; Raja, R.; Lopez-Ortiz, F.; Angel del Aguila-Sanchez, M.; Alajarin, M. π-Insertion Reactions of Benzynes into P:N and P:S Double Bonds. European Journal of Organic Chemistry, 2014, 5, 1084–1095. http://doi.org/10.1002/ejoc.201301481
·Vidal, A.; Marin-Luna, M.; Alajarin, M. Tandem Processes in C-Aryl Ketenes and Ketenimines Triggered by [1,5|-Hydride-Like Migration of an Acetal Hydrogen Atom. European Journal of Organic Chemistry, 2014, 4, 878–886. http://doi.org/10.1002/ejoc.201301501
·Alajarin, M.; Marin-Luna, M.; Vidal, A. Unexpected new examples of the Thyagarajan-Majumdar tandem cyclization of aryl propargyl sulfoxides. ARKIVOC, 2014, 2, 36–43. http://doi.org/10.3998/ark.5550190.p008.037
·Martinez-Cuezva, A.; Berna, J.; Orenes, R.-A.; Pastor, A.; Alajarin, M. Small-Molecule Recognition for Controlling Molecular Motion in Hydrogen-Bond-Assembled Rotaxanes. Angewandte Chemie International Edition, 2014, 53, 6762–6767. http://doi.org/10.1002/anie.201402962
·Berna, J.; Franco-Pujante, C.; Alajarin, M. Competitive binding for triggering a fluorescence response in a hydrazodicarboxamide-based [2]rotaxane. Organic & Biomolecular Chemistry, 2014, 12, 474–478. http://doi.org/10.1039/C3OB41807C
·Alajarin, M.; Bonillo, B.; Marin-Luna, M.; Sanchez-Andrada, P.; Vidal, A. Thermal Cyclization of Phenylallenes That Contain ortho-1,3-Dioxolan-2-yl Groups: New Cascade Reactions Initiated by 1,5-Hydride Shifts of Acetalic H Atoms. Chemistry - A European Journal, 2013, 19, 16093–16103. http://doi.org/10.1002/chem.201301608
·Alajarin, M.; Cabrera, J.; Sanchez-Andrada, P.; Bautista, D.; Pastor, A. 5-Alkenylthiazoles as In-Out Dienes in Polar [4+2] Cycloaddition Reactions. European Journal of Organic Chemistry, 2013, 33, 7500–7511. http://doi.org/10.1002/ejoc.201300925
·Alajarin, M.; Cabrera, J.; Sanchez-Andrada, P.; Orenes, R.-A.; Pastor, A. 4-Alkenyl-2-aminothiazoles: Smart Dienes for Polar [4 + 2] Cycloadditions. European Journal of Organic Chemistry, 2013, 3, 474–489. http://doi.org/10.1002/ejoc.201201185
·Alajarin, M.; Bonillo, B.; Orenes, R.-A.; Ortin, M.-M.; Vidal, A. 1,5-(H, RO, RS) shift/6π-electrocyclic ring closure tandem processes on N-[(α-heterosubstituted)-2-tolyl]ketenimines: a case study of relative migratory aptitudes and activating effects. Organic & Biomolecular Chemistry, 2012, 10, 9523–9537. http://doi.org/10.1039/c2ob27010b
·Keglevich, G.; Alajarin, M.; Vanelle, P.; D’Auria, M.; Yus, M.; Torok, B. Tribute to a living legend. Letters in Organic Chemistry, 2012, 9, vi. http://doi.org/10.2174/157017812802139618
·Alajarin, M.; Lopez-Leonardo, C.; Llamas-Lorente, P.; Raja, R.; Bautista, D.; Orenes, R.-A. Palladium complexes derived from N,N-bidentate NH-iminophosphorane ligands: synthesis and use as catalysts in the Sonogashira reaction. Dalton Transactions, 2012, 41, 12259–12269. http://doi.org/10.1039/c2dt31290e
·Alajarin, M.; Marin-Luna, M.; Vidal, A. Recent Highlights in Ketenimine Chemistry. European Journal of Organic Chemistry, 2012, 29, 5637–5653. http://doi.org/10.1002/ejoc.201200383
·Alajarin, M.; Bonillo, B.; Marin-Luna, M.; Sanchez-Andrada, P.; Vidal, A.; Orenes, R.-A. Tandem [1,5]-H shift/6π-electrocyclizations of ketenimines bearing 1,3-oxathiane units. Computational assessment of the experimental diastereoselection. Tetrahedron, 2012, 68, 4672–4681. http://doi.org/10.1016/j.tet.2012.04.021
·Alajarin, M.; Orenes, R.-A.; Howard, J. A. K.; Spencer, E. C.; Steed, J. W.; Pastor, A. Novel Capsular Aggregates from Flexible Tripodal Triureas with Cs Symmetry. Chemistry - A European Journal, 2012, 18, 2389–2397, S2389/1–S2389/17. http://doi.org/10.1002/chem.201102246
·Berna, J.; Alajarin, M.; Marin-Rodriguez, C.; Franco-Pujante, C. Redox divergent conversion of a [2]rotaxane into two distinct degenerate partners with different shuttling dynamics. Chemical Science, 2012, 3, 2314–2320. http://doi.org/10.1039/c2sc20488f
·Berna, J.; Alajarin, M.; Martinez-Espin, J. S.; Buriol, L.; Martins, M. A. P.; Orenes, R.-A. Dampened circumrotation by CH···π interactions in hydrogen bonded [2]rotaxanes. Chemical Communications, 2012, 48, 5677–5679. http://doi.org/10.1039/c2cc32092d
·Alajarin, M.; Lopez-Leonardo, C.; Raja, R.; Orenes, R.-A. Insertion of Benzynes into the P:N Bond of P-Alkenyl(alkynyl)-λ5-phosphazenes. Organic Letters, 2011, 13, 5668–5671. http://doi.org/10.1021/ol202395s
·Alajarin, M.; Orenes, R.-A.; Pastor, A. Self-assembly of tris(2-ureidobenzyl)amines with C1 symmetry. Structural Chemistry, 2011, 22, 977–981. http://doi.org/10.1007/s11224-011-9787-y
·Alajarin, M.; Bonillo, B.; Ortin, M.-M.; Orenes, R.-A.; Vidal, A. Unprecedented intramolecular [3 + 2] cycloadditions of azido-ketenimines and azido-carbodiimides. Synthesis of indolo[1,2-a]quinazolines and tetrazolo[5,1-b]quinazolines. Organic & Biomolecular Chemistry, 2011, 9, 6741–6749. http://doi.org/10.1039/c1ob05745f
·Alajarin, M.; Marin-Luna, M.; Ortin, M.-M.; Sanchez-Andrada, P.; Vidal, A. retro-Cheletropic ene reactions with 2-carbena-1,3-dioxolane as chelefuge. Tetrahedron, 2011, 67, 5590–5595. http://doi.org/10.1016/j.tet.2011.05.119
·Caccamese, S.; Barrano, G. B., Alajarin, M., Bonillo, B.; Vidal, A.; Bruno, G.; … Rosini, C. Determination of the absolute configuration of the enantiomers of dihydroquinolines, isolated by chiral chromatography, by non empirical analysis of circular dichroism spectra and X-ray analysis. Tetrahedron: Asymmetry, 2011, 22, 270–276. http://doi.org/10.1016/j.tetasy.2011.01.010
·Alajarin, M.; Bonillo, B.; Ortin, M.-M.; Sanchez-Andrada, P.; Vidal, A. Tandem 1,5-Hydride Shift/6π Electrocyclization of Ketenimines and Carbodiimides Substituted with Cyclic Acetal and Dithioacetal Functions: Experiments and Computations. European Journal of Organic Chemistry, 2011, 10, 1896–1913, S1896/1–S1896/95. http://doi.org/10.1002/ejoc.201001372
·Alajarin, M.; Marin-Luna, M.; Vidal, A. Functionalization of Acetalic C(sp3)-H Bonds by Scandium(III) Triflate-Catalyzed Intramolecular Redox Reactions: Tandem 1,4-Hydride Transfer/1,5-Cyclization Processes Leading to Protected 1-Indanones. Advanced Synthesis & Catalysis, 2011, 353, 557–562. http://doi.org/10.1002/adsc.201000812
·Bodis, P.; Yeremenko, S.; Berna, J.; Buma, W. J.; Leigh, D. A.; Woutersen, S. Bimodal dynamics of mechanically constrained hydrogen bonds revealed by vibrational photon echoes. Journal of Chemical Physics, 2011, 134, 134504/1-134504/7. http://doi.org/10.1063/1.3569761